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(+)-Valienamine

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Origin: China

Cas No: 38231-86-6

Specification: 99%min

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  • Products Specification
  • Product Description

  • Property

    CAS No.: 38231-86-6 Formula: C7H13NO4 Molecular Weight: 175.18200

    Description

    Valienamine is a C-7 aminocyclitol found as a substructure of pseudooligosaccharides such as the antidiabetic drug acarbose and the antibiotic validamycin. It can be found in Actinoplanes species.
    It is an intermediate formed by microbial degradation of validamycins.

    Basic Info

    Chemical Name (+)-Valienamine
    Synonyms

    Valienamine;
    (1S,2S,3R,6S)-6-Amino-4-(hydroxymethyl)cyclohex-4-ene-1,2,3-triol;

    CAS No. 38231-86-6
    Molecular Formula C7H13NO4
    Molecular Weight 175.18200
    PSA 106.94000
    LogP -1.97100

    Properties

    Appearance & Physical State Slightly Yellow Solid
    Density 1.525 g/cm3
    Boiling Point 377.3ºC at 760 mmHg
    Flash Point 182ºC
    Refractive Index 1.648

    Safety Info

    HS Code 2922199090

    Synthesis Route

    D-glucopyranose→validamine+(+)-Valienamine
    4-(Hydroxymethyl)-6-{[2,3,4-trihydroxy-5-(hydroxymethyl)cyclohexy l]amino}-4-cyclohexene-1,2,3-triol→validamine+(+)-Valienamine
    validamycin A→4-(Hydroxymethyl)-6-{[2,3,4-trihydroxy-5-(hydroxymethyl)cyclohexy l]amino}-4-cyclohexene-1,2,3-triol+validamine

    Precursor

    1,1'-bis-valienamine
    4-(Hydroxymethyl)-6-{[2,3,4-trihydroxy-5-(hydroxymethyl)cyclohexy l]amino}-4-cyclohexene-1,2,3-triol
    ((3S,4S,5S,6R)-4,5,6-tris(benzyloxy)-3-(4-methylphenylsulfonamido)cyclohex-1-en-1-yl)methyl benzoate
    1D-(1,3,6/2)-6-amino-4-benzyloxymethyl-1,2,3-tri-O-benzyltrihydroxycyclohex-4-ene

    Downstream Product

    validamine
    (1S,2S,3R,4S,5S)-5-amino-1-(hydroxymethyl)cyclohexane-1,2,3,4-tetrol
    6,7,8-trihydroxy-5-(hydroxymethyl)-4-oxa-2-azabicyclo[3.3.1]nonan-3-one
    Validamin

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