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Chloro(1,5-cyclooctadiene)rhodium(I) dimer

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Origin: China

Cas No: 12092-47-6

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 50 mt/month

Lead time: 7 days for OEM, 3 days for ready goods

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Products Specification
Product Description

Quick Details
CAS No.:
12092-47-6
MF:
C16H24Cl2Rh2
EINECS No.:
/
Place of Origin:
China
Purity:
41.7%min
Appearance:
white powder
Application:
/
Brand Name:
/
Model Number:
12092-47-6
Product Name:
chloro(1,5-cyclooctadiene)rhodium(i) dimer
Packaging&Delivery
Selling Units:
Single item
Single package size:
20X20X30 cm
Single gross weight:
1.000 kg
Lead Time:
Quantity(Grams) 1 - 1000 >1000
Est. Time(days) 5 To be negotiated

Property

CAS No.: 12092-47-6 Formula: C16H24Cl2Rh2 Molecular Weight: 493.07900

Description

Cyclooctadiene rhodium chloride dimer is the organorhodium compound with the formula Rh2Cl2(C8H12)2, commonly abbreviated [RhCl(COD)]2 or Rh2Cl2(COD)2. This yellow-orange, air-stable compound is a widely used precursor to homogeneous catalysts.

Basic Info

Chemical Name	Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Synonyms	Bis(1,5-cyclooctadiene)dirhodium(I) Dichloride; (1Z,5Z)-cycloocta-1,5-diene,rhodium,dichloride; (1,5-Cyclooctadiene)rhodium chloride dimer; 1,5-Cyclooctadiene Rhodium(I) Chloride Dimer; Chloro(1,5-Cyclooctadiene)Rhodium(I) Dimer;
CAS No.	12092-47-6
Molecular Formula	C16H24Cl2Rh2
Molecular Weight	493.07900
PSA	0.00000
LogP	-0.64640

Properties

Appearance & Physical State	Yellow-orange crystalline powder crystalline powder.
Boiling Point	153.5ºC at 760mmHg
Melting Point	255ºC (dec.)
Flash Point	31.7ºC
Stability	Stable under normal temperatures and pressures.
Storage Condition	2-8ºC

Safety Info

Safety Statements	S26-S37/39
Risk Statements	R36/37/38
Hazard Codes	Xi

Synthesis Route

(2Z,6E,10E)-1-bromo-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraene→Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Dichloro(1,5-cyclooctadiene)palladium(II)+→Chloro(1,5-cyclooctadiene)rhodium(I) dimer+
rhodium{C6H3(CH2NMe2)2-o,o'}(1,5-cyclooctadiene)→Chloro(1,5-cyclooctadiene)rhodium(I) dimer+HgCl{C6H3(CH2NMe2)2-o,o'}

Precursor

silver,hexafluorophosphate
Dichloro(1,5-cyclooctadiene)palladium(II)
(2Z,6E,10E)-1-bromo-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraene

Downstream Product

acetonitrile,(1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate
(1Z,5Z)-cycloocta-1,5-diene,dichlororhodium(1-),rhodium,N,N,N',N'-tetramethylethane-1,2-diamine
2,2'-[1,2-Phenylenebis(oxy)]bis(1,3,2-benzodioxaborole)
boron,triphenylphosphane

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